Haloalkane and Haloarenes-3 | 12th | IIT-JEE |NEET-Best IIT-JEE ,NEET Coaching In Varanasi.

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Certainly! Haloalkanes and haloarenes are important topics in organic chemistry, especially for IIT-JEE and NEET exams. Here’s a concise overview to help you with these compounds: Best IIT-JEE ,NEET Coaching In Varanasi.

1. Haloalkanes (Alkyl Halides)

Structure and Nomenclature:

  • Haloalkanes are organic compounds where one or more halogen atoms (F, Cl, Br, I) replace hydrogen atoms in alkanes. Best IIT-JEE ,NEET Coaching In Varanasi.
  • The general formula is CnH2n+1XC_nH_{2n+1}XCn​H2n+1​X, where XXX is a halogen. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Naming: Use the IUPAC system. The halogen is named as a substituent (fluoro-, chloro-, bromo-, iodo-). Best IIT-JEE ,NEET Coaching In Varanasi.

Classification:

  • Primary (1°): The carbon attached to the halogen is bonded to one other carbon (e.g., ethyl chloride). Best IIT-JEE ,NEET Coaching In Varanasi.
  • Secondary (2°): The carbon attached to the halogen is bonded to two other carbons (e.g., isopropyl bromide). Best IIT-JEE ,NEET Coaching In Varanasi.
  • Tertiary (3°): The carbon attached to the halogen is bonded to three other carbons (e.g., tert-butyl chloride). Best IIT-JEE ,NEET Coaching In Varanasi.

Physical Properties:

  • Higher boiling and melting points compared to alkanes due to dipole-dipole interactions. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Generally, they are more soluble in organic solvents and less soluble in water. Best IIT-JEE ,NEET Coaching In Varanasi.

Chemical Reactions:

  • Nucleophilic Substitution (SN1 and SN2):
    • SN1: Occurs in two steps; involves carbocation intermediates, favored in tertiary haloalkanes. Best IIT-JEE ,NEET Coaching In Varanasi.
    • SN2: Occurs in one step; involves a single transition state with a backside attack, favored in primary haloalkanes. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Elimination Reactions (E1 and E2):
    • E1: Occurs in two steps; involves carbocation formation, favored in tertiary haloalkanes. Best IIT-JEE ,NEET Coaching In Varanasi.
    • E2: Occurs in one step; involves a strong base abstracting a proton, favored in primary and secondary haloalkanes. Best IIT-JEE ,NEET Coaching In Varanasi.

2. Haloarenes (Aryl Halides)

Structure and Nomenclature:

  • Haloarenes are aromatic compounds where a halogen replaces one hydrogen atom in an aromatic ring. Best IIT-JEE ,NEET Coaching In Varanasi.
  • The general formula is CnHn−1XC_nH_{n-1}XCn​Hn−1​X, where XXX is a halogen. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Naming: The halogen is named as a substituent (fluoro-, chloro-, bromo-, iodo-). The position of the substituent is indicated by numbers (e.g., chlorobenzene). Best IIT-JEE ,NEET Coaching In Varanasi.

Physical Properties:

  • They have higher melting and boiling points than alkanes due to the presence of the halogen but are less polar compared to haloalkanes. Best IIT-JEE ,NEET Coaching In Varanasi.
  • They are generally less reactive towards nucleophiles compared to haloalkanes due to the resonance stabilization of the aryl ring. Best IIT-JEE ,NEET Coaching In Varanasi.

Chemical Reactions:

  • Nucleophilic Substitution: Generally less reactive. Reactivity is enhanced by electron-withdrawing groups on the ring (e.g., NO₂). Best IIT-JEE ,NEET Coaching In Varanasi.
    • Benzyne Mechanism: Some haloarenes react via a benzyne intermediate under extreme conditions. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Electrophilic Substitution: Haloarenes are more reactive towards electrophiles compared to benzene due to the activating effect of the halogen (although they are deactivating overall).
    • Halogens are ortho- and para-directing due to their electron-donating resonance effect. Best IIT-JEE ,NEET Coaching In Varanasi.

Important Points for Exams:

  • Reactivity Trends: Haloalkanes react more readily in nucleophilic substitution and elimination reactions compared to haloarenes. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Mechanisms: Understand the mechanisms (SN1, SN2, E1, E2) and how they depend on the structure of the haloalkane or haloarene. Best IIT-JEE ,NEET Coaching In Varanasi.
  • Resonance and Inductive Effects: Know how these effects influence the reactivity and stability of haloarenes. Best IIT-JEE ,NEET Coaching In Varanasi.

Practice Problems:

  1. Predict the Major Product: For a given haloalkane or haloarene reacting with a nucleophile or base. Best IIT-JEE ,NEET Coaching In Varanasi.
  2. Mechanism Questions: Explain the mechanism of a given reaction involving haloalkanes or haloarenes. Best IIT-JEE ,NEET Coaching In Varanasi.
  3. Reactivity Comparison: Compare the reactivity of different haloalkanes or haloarenes in a given reaction. Best IIT-JEE ,NEET Coaching In Varanasi.

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